{"id":860,"date":"2025-03-05T13:00:00","date_gmt":"2025-03-05T12:00:00","guid":{"rendered":"https:\/\/personal.unizar.es\/evange\/?p=860"},"modified":"2025-03-06T17:38:32","modified_gmt":"2025-03-06T16:38:32","slug":"molecule-based-coolant-on-a-jacs-cover","status":"publish","type":"post","link":"https:\/\/personal.unizar.es\/evange\/2025\/03\/05\/molecule-based-coolant-on-a-jacs-cover\/","title":{"rendered":"Molecule-based coolant on a JACS cover"},"content":{"rendered":"\n<p class=\"wp-block-paragraph\">&#8216;A Triangular Frustrated Eu(II)\u2013Organic Framework for Sub-Kelvin Magnetic Refrigeration&#8217; by Anna S. Manvell, Maja A. Dunstan, David Gracia, Jakub Hrub\u00fd, Mariusz Kubus, James N. McPherson, Elias Palacios, H\u00f8gni Weihe, Stephen Hill, J\u00fcrgen Schnack<strong>,\u00a0<\/strong>Marco Evangelisti, Kasper S. Pedersen, Journal of the American Chemical Society <strong>147<\/strong>, 7597 (2025); <a href=\"https:\/\/doi.org\/10.1021\/jacs.4c17003\" target=\"_blank\" rel=\"noreferrer noopener\">https:\/\/doi.org\/10.1021\/jacs.4c17003<\/a><a href=\"\"><\/a><\/p>\n\n\n\n<p class=\"wp-block-paragraph\">This work unveils a new design principle for dense magnetic refrigerants, leveraging symmetry control of lanthanide-based networks through molecular templation. The self-assembly reaction of Eu<sup>2+<\/sup>&nbsp;with ditopic pyrazine ligands, in the presence of large Ba<sup>2+<\/sup>&nbsp;ions, yields a structurally unique two-dimensional&nbsp;triangular tessellation of the metal ions. This structure, templated by a small concentration of heterometal ions, is unprecedented in reticular chemistry and has significant material consequences: (<em>1<\/em>) a unique coordination geometry with elongated Eu<sup>2+<\/sup>-ligand distances, which leads to (<em>2<\/em>) antiferromagnetic interactions and (<em>3<\/em>) easy-plane magnetic anisotropy, whose interplay promotes (<em>4<\/em>) geometric frustration of the electronic spins due to high crystallographic symmetry. Finally, (<em>5<\/em>) Eu<sup>2+<\/sup>&nbsp;carries a large magnetic spin moment of&nbsp;<em>s<\/em>&nbsp;= 7\/2, which has been central to the development of coolant materials for adiabatic demagnetization refrigerators. The long-sought goal of achieving high entropies at very-low temperatures is here accomplished through geometric frustration, allowing for cooling to temperatures that fall below the magnetic interaction strength. Demagnetization experiments reach temperatures as low as 0.17 K, while long-range magnetic order is anticipated to occur below 0.09 K, despite a Curie-Weiss temperature of 0.24 K.&nbsp;<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">These findings hold significant promise for applications in sub-Kelvin cryogenic cooling, a field that is gaining increasing relevance.&nbsp;This research not only enhances the understanding of f-block chemistry, magnetic frustration, and magnetic refrigeration but also outlines practical pathways for material innovation.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>&#8216;A Triangular Frustrated Eu(II)\u2013Organic Framework for Sub-Kelvin Magnetic Refrigeration&#8217; by Anna S. Manvell, Maja A. Dunstan, David Gracia, Jakub Hrub\u00fd, Mariusz Kubus, James N. McPherson, Elias Palacios, H\u00f8gni Weihe, Stephen Hill, J\u00fcrgen Schnack,\u00a0Marco Evangelisti, Kasper S. Pedersen, Journal of the American Chemical Society 147, 7597 (2025); https:\/\/doi.org\/10.1021\/jacs.4c17003 This work unveils a new design principle for<\/p>\n<div class=\"more-link\">\n\t\t\t\t <a href=\"https:\/\/personal.unizar.es\/evange\/2025\/03\/05\/molecule-based-coolant-on-a-jacs-cover\/\" class=\"link-btn theme-btn\"><span>Read More <\/span> <i class=\"fa fa-caret-right\"><\/i><\/a>\n\t\t\t<\/div>\n","protected":false},"author":1,"featured_media":872,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[13],"tags":[16,17,15],"class_list":["post-860","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-publication","tag-magnetocalorics","tag-mof","tag-molecular"],"_links":{"self":[{"href":"https:\/\/personal.unizar.es\/evange\/wp-json\/wp\/v2\/posts\/860","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/personal.unizar.es\/evange\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/personal.unizar.es\/evange\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/personal.unizar.es\/evange\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/personal.unizar.es\/evange\/wp-json\/wp\/v2\/comments?post=860"}],"version-history":[{"count":7,"href":"https:\/\/personal.unizar.es\/evange\/wp-json\/wp\/v2\/posts\/860\/revisions"}],"predecessor-version":[{"id":875,"href":"https:\/\/personal.unizar.es\/evange\/wp-json\/wp\/v2\/posts\/860\/revisions\/875"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/personal.unizar.es\/evange\/wp-json\/wp\/v2\/media\/872"}],"wp:attachment":[{"href":"https:\/\/personal.unizar.es\/evange\/wp-json\/wp\/v2\/media?parent=860"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/personal.unizar.es\/evange\/wp-json\/wp\/v2\/categories?post=860"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/personal.unizar.es\/evange\/wp-json\/wp\/v2\/tags?post=860"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}