2011 - 2015

Size-dependent magnetic ordering and spin-dynamics in DyPO₄ and GdPO₄ nanoparticles

M. Evangelisti, T. G. Sorop, O. N. Bakharev, D. Visser, A. D. Hillier, J. J. Alonso, M. Haase, L. A. Boatner, and L. J. de Jongh
Physical Review B 84, 094408 (2011).

Molecular prototypes for spin-based CNOT and SWAP quantum gates

F. Luis, A. Repollés, M. J. Martínez- Pérez, D. Aguilà, O. Roubeau, D. Zueco, P. J. Alonso, M. Evangelisti, A. Camón, J. Sesé, L. A. Barrios, and G. Aromí
Physical Review Letters 107, 117203 (2011).

Short-range correlations in d-f cyanido-bridged assemblies with XY and XY-Heisenberg anisotropy

S. Tanase, M. Evangelisti and L. J. de Jongh
Dalton Transactions 40, 8407 (2011).

A molecular pair of [GdNi₃] tetrahedra bridged by water molecules

A. Hosoi, Y. Yukawa, S. Igarashi, S. J. Teat, O. Roubeau, M. Evangelisti, E. Cremades, E. Ruiz, L. A. Barrios, and G. Aromí
Chemistry - A European Journal 17, 8264 (2011).

Cryogenic magnetocaloric effect in a ferromagnetic molecular dimer

M. Evangelisti, O. Roubeau, E. Palacios, A. Camón, T. N. Hooper, E. K. Brechin, and J. J. Alonso
Angewandte Chemie International-Edition 50, 6606 (2011).
Link to BACK COVER.

Molecular coolers: The case for [Cu^II₅Gd^III₄]

S. K. Langley, N. F. Chilton, B. Moubaraki, T. Hooper, E. K. Brechin, M. Evangelisti, and K. S. Murray
Chemical Science 2, 1166 (2011).

Chromium(III) stars and butterflies: Synthesis, structural and magnetic studies of tetra-metallic clusters

L. J. Batchelor, M. Sander, F. Tuna, M. Helliwell, F. Moro, J. van Slageren, E. Burzurí, O. Montero, M. Evangelisti, F. Luis, and E. J. L. McInnes
Dalton Transactions 40, 5278 (2011).

Enhancing U_eff in oxime-bridged [Mn^III₆Ln^III₂] hexagonal prisms

G. Rigaux, R. Inglis, S. Morrison, A. Prescimone, C. Cadiou, M. Evangelisti, and E. K. Brechin
Dalton Transactions 40, 4797 (2011).

Large magnetocaloric effect in a Wells-Dawson type {Ni₆Gd₆P₆} cage

Y.-Z. Zheng, M. Evangelisti and R. E. P. Winpenny
Angewandte Chemie International-Edition 50, 3692 (2011).

Low-temperature specific heat of Nd_1-xCa_xB₆ single crystals

J. Stankiewicz, M. Evangelisti and Z. Fisk
Physical Review B 83, 113108 (2011).

Co-Gd phosphonate complexes as magnetic refrigerants

Y.-Z. Zheng, M. Evangelisti and R. E. P. Winpenny
Chemical Science 2, 99 (2011).
Link to FRONT COVER.

Lanthanoid single-ion magnets based on polyoxometalates with a 5-fold symmetry: The series [LnP₅W₃₀O₁₁₀]^12- (Ln³⁺ = Tb, Dy, Ho, Er, Tm, and Yb)

S. Cardona-Serra, J. M. Clemente-Juan, E. Coronado, A. Gaita-Ariño, A. Camón, M. Evangelisti, F. Luis, M. J. Martínez-Pérez, and J. Sesé
Journal of the American Chemical Society 134, 14982 (2012).

Fluoride-bridged {Ln₂Cr₂} polynuclear complexes from semi-labile mer-[CrF₃(py)₃] and [Ln(hfac)₃(H₂O)₂]

C. Aa. Thuesen, K. S. Pedersen, M. Schau-Magnussen, M. Evangelisti, J. Vibenholt, S. Piligkos, H. Weihe, and J. Bendix
Dalton Transactions 41, 11284 (2012).

Fragmenting gadolinium: Mononuclear polyoxometalate-based magnetic coolers for ultra-low temperatures

M.-J. Martínez-Pérez, O. Montero, M. Evangelisti, F. Luis, J. Sesé, S. Cardona-Serra, and E. Coronado
Advanced Materials 24, 4301 (2012).

Electronic and magnetic properties of Mn₁₂ molecular magnets on sulphonate and carboxylic acid pre-functionalized gold surfaces

F. Moro, R. Biagi, V. Corradini, M. Evangelisti, A. Gambardella, V. De Renzi, U. del Pennino, E. Coronado, A. Forment-Aliaga, and F. M. Romero
The Journal of Physical Chemistry C 116, 14936 (2012).

A spin crossover ferrous complex with ordered magnetic ferric anions

O. Roubeau, M. Evangelisti, and E. Natividad
Chemical Communications 48, 7604 (2012).

Increasing the dimensionality of cryogenic molecular coolers: Gd-based polymers and metal-organic frameworks

G. Lorusso, M. A. Palacios, G. S. Nichol, E. K. Brechin, O. Roubeau, and M. Evangelisti
Chemical Communications 48, 7592 (2012).

Kondo physics in a rare earth ion with well localized 4f electrons

J. Stankiewicz, M. Evangelisti, Z. Fisk, P. Schlottmann, and L. P. Gor'kov
Physical Review Letters 108, 257201 (2012).

Gd-based single-ion magnets with tunable magnetic anisotropy: Molecular design of spin qubits

M.-J. Martínez-Pérez, S. Cardona-Serra, C. Schlegel, F. Moro, P. J. Alonso, H. Prima-García, J. M. Clemente-Juan, M. Evangelisti, A. Gaita-Ariño, J. Sesé, J. van Slageren, E. Coronado, and F. Luis
Physical Review Letters 108, 247213 (2012).
Selected as an Editors' Suggestion.

Realization of the 1D anisotropic XY model in a Tb(III)-W(V) chain compound

E. Pasca, T. Roscilde, M. Evangelisti, E. Burzurí, F. Luis, L. J. de Jongh, and S. Tanase
Physical Review B 85, 184434 (2012).

Fluoride bridges as structure-directing motifs in 3d-4f cluster chemistry

T. Birk, K. S. Pedersen, C. Aa. Thuesen, T. Weyhermüller, M. Schau-Magnussen, S. Piligkos, H. Weihe, S. Mossin, M. Evangelisti, and J. Bendix
Inorganic Chemistry 51, 5435 (2012).

The importance of being exchanged: [Gd^III₄M^II₈(OH)₈(L)₈(O₂CR)₈]⁴⁺ clusters for magnetic refrigeration

T. N. Hooper, J. Schnack, S. Piligkos, M. Evangelisti, and E. K. Brechin
Angewandte Chemie International-Edition 51, 4633 (2012).

Co-Ln mixed-metal phosphonate grids and cages as molecular magnetic refrigerants

Y.-Z. Zheng, M. Evangelisti, F. Tuna, and R. E. P. Winpenny
Journal of the American Chemical Society 134, 1057 (2012).

Calix[4]arene-supported rare earth octahedra

S. Sanz, R. D. McIntosh, C. M. Beavers, S. J. Teat, M. Evangelisti, E. K. Brechin, and S. J. Dalgarno
Chemical Communications 48, 1449 (2012).

A molecular [Mn₁₄] coordination cluster featuring two slowly relaxing nanomagnets

J. Sánchez Costa, L. A. Barrios, G. A. Craig, S. J. Teat, F. Luis, O. Roubeau, M. Evangelisti, A. Camón, and G. Aromí
Chemical Communications 48, 1413 (2012).

Fingerprinting the oxidation state of U(IV) by emission spectroscopy

E. Hashem, G. Lorusso, M. Evangelisti, T. McCabe, C. Schulzke, J. A. Platts, and R. J. Baker
Dalton Transactions 42, 14677 (2013).

Molecular nanoscale magnetic refrigerants: A ferrimagnetic {Cu^II₁₅Gd^III₇} cage-like cluster from the use of pyridine-2,6-dimethanol

D. Dermitzaki, G. Lorusso, C. P. Raptopoulou, V. Psycharis, A. Escuer, M. Evangelisti, S. P. Perlepes, and T. C. Stamatatos
Inorganic Chemistry 52, 10235 (2013).

A dense metal-organic framework for enhanced magnetic refrigeration

G. Lorusso, J. W. Sharples, E. Palacios, O. Roubeau, E. K. Brechin, R. Sessoli, A. Rossin, F. Tuna, E. J. L. McInnes, D. Collison, and M. Evangelisti
Advanced Materials 25, 4653 (2013).

Surface-confined molecular coolers for cryogenics

G. Lorusso, M. Jenkins, P. González-Monje, A. Arauzo, J. Sesé, D. Ruiz-Molina, O. Roubeau, and M. Evangelisti
Advanced Materials 25, 2984 (2013).
Link to FRONT COVER.

A ferromagnetically coupled diphenoxo-bridged Gd³⁺-Mn²⁺ dinuclear complex with a large magneto-caloric effect

E. Colacio, J. Ruiz, G. Lorusso, E. K. Brechin, and M. Evangelisti
Chemical Communications 49, 3845 (2013).

Cryogenic magnetocaloric effect in the Fe₁₇ molecular nanomagnet

I. A. Gass, E. K. Brechin, and M. Evangelisti
Polyhedron 52, 1177 (2013).

Magnetic structure and magnetocalorics of GdPO₄

E. Palacios, J. A. Rodríguez-Velamazán, M. Evangelisti, G. J. McIntyre, G. Lorusso, D. Visser, L. J. de Jongh, and L. A. Boatner
Physical Review B 90, 214423 (2014).
Selected as an Editors' Suggestion.

Synthesis, structure and magnetism of a family of heterometallic {Cu₂Ln₇} and {Cu₄Ln₁₂} (Ln = Gd, Tb and Dy) complexes: The Gd analogues exhibiting a large magnetocaloric effect

S. K. Langley, B. Moubaraki, C. Tomasi, M. Evangelisti, E. K. Brechin, and K. S. Murray
Inorganic Chemistry 53, 13154 (2014).

Single-molecule magnet behavior and magnetocaloric effect in ferromagnetically coupled Ln^III-Ni^II-Ni^II-Ln^III (Ln^III = Dy^III and Gd^III) linear complexes

C. Meseguer, S. Titos-Padilla, M. Hänninen, R. Casas, A. J. Mota, M. Evangelisti, J. Ruiz, and E. Colacio
Inorganic Chemistry 53, 12092 (2014).

Quantum signatures of a molecular nanomagnet in direct magnetocaloric measurements

J. W. Sharples, D. Collison, E. J. L. McInnes, J. Schnack, E. Palacios, and M. Evangelisti
Nature Communications 5, 5321 (2014).

Rational electrostatic design of easy-axis magnetic anisotropy in a Zn^II–Dy^III–Zn^II single-molecule magnet with high energy barrier

I. Oyarzabal, J. Ruiz, J. M. Seco, M. Evangelisti, A. Camón, E. Ruiz, D. Aravena, and E. Colacio
Chemistry - A European Journal 20, 14262 (2014).
Selected as Hot Paper; Link to FRONTISPIECE.

Thiocyanate complexes of uranium in multiple oxidation states: A combined structural, magnetic, spectroscopic, spectroelectrochemical and theoretical study

E. Hashem, J. A. Platts, F. Hartl, G. Lorusso, M. Evangelisti, C. Schulzke, and R. J. Baker
Inorganic Chemistry 53, 8624 (2014).

Comment on "Theoretical design of molecular nanomagnets for magnetic refrigeration" [Appl. Phys. Lett. 103, 202410 (2013)]

M. Evangelisti, G. Lorusso and E. Palacios
Applied Physics Letters 105, 046101 (2014).

Cryogenic magneto-­caloric effect and magneto-structural correlations in carboxylate-­bridged Gd(III) compounds

O. Roubeau, G. Lorusso, S. J. Teat, and M. Evangelisti
Dalton Transactions 43, 11502 (2014).

Two C₃-symmetric Dy₃^III complexes with triple di-µ-methoxo-µ-phenoxo bridges, magnetic ground state and single-molecule magnetic behavior

M. M. Hänninen, A. J. Mota, D. Aravena, E. Ruiz, R. Sillanpää, A. Camón, M. Evangelisti, and E. Colacio
Chemistry - A European Journal 20, 8410 (2014).

A multifunctional magnetic material under pressure

J. A. Rodríguez-Velamazán, O. Fabelo, C. M. Beavers, E. Natividad, M. Evangelisti, and O. Roubeau
Chemistry - A European Journal 20, 7956 (2014).
Link to BACK COVER.

Closely-related Zn^II₂Ln^III₂ complexes (Ln^III = Gd, Yb) with either magnetic refrigerant or luminescent single-molecule magnet properties

J. Ruiz, G. Lorusso, M. Evangelisti, E. K. Brechin, S. J. A. Pope, and E. Colacio
Inorganic Chemistry 53, 3586 (2014).

CO₂ as a reaction ingredient for the construction of metal cages: A carbonate-panelled [Gd₆Cu₃] tridiminished icosahedron

T. N. Hooper, R. Inglis, M. A. Palacios, G. B. Nichol, M. B. Pitak, S. J. Coles, G. Lorusso, M. Evangelisti, and E. K. Brechin
Chemical Communications 50, 3498 (2014).

Combining oxime-based [Mn₆] clusters with cyanometalates: 1D chains of [Mn₆] SMMs from [M(CN₂)]^- (M= Au, Ag)

S. Sanz, J. M. Frost, G. Lorusso, M. Evangelisti, M. B. Pitak, S. J. Coles, G. S. Nichol, and E. K. Brechin
Dalton Transactions 43, 4622 (2014).
Link to INSIDE FRONT COVER.

Fluoride-bridged {Gd^III₃M^III₂} (M = Cr, Fe, Ga) molecular coolers

K. S. Pedersen, G. Lorusso, J. J. Morales, T. Weyhermüller, S. Piligkos, S. K. Singh, M. Schau-Magnussen, G. Rajaraman, M. Evangelisti, and J. Bendix
Angewandte Chemie International-Edition 53, 2394 (2014).
Link to INSIDE FRONT COVER.

Molecule-based magnetic coolers: Measurement, design and application

M. Evangelisti
J. Bartolomé, F. Luis and J. F. Fernández (eds.), Molecular Magnets, NanoScience and Technology, Springer-Verlag, Berlin, Heidelberg, pp. 365-387, (2014).

Low temperature magnetic properties and spin dynamics in single crystals of Cr₈Zn antiferromagnetic molecular rings

F. Adelnia, A. Chiesa, S. Bordignon, S. Carretta, A. Ghirri, A. Candini, C. Cervetti, M. Evangelisti, M. Affronte, I. Sheikin, R. Winpenny, G. Timco, F. Borsa, and A. Lascialfari
The Journal of Chemical Physics 143, 244321 (2015).

Decanuclear Ln₁₀ wheels and vertex-shared spirocyclic Ln₅ cores: Synthesis, structure, SMM behavior, and MCE properties

S. Das, A. Dey, S. Kundu, S. Biswas, R. S. Narayanan, S. Titos-Padilla, G. Lorusso, M. Evangelisti, E. Colacio, and V. Chandrasekhar
Chemistry - A European Journal 21, 16955 (2015).

‘All three-in-one’: Ferromagnetic interactions, single-molecule magnetism and magnetocaloric properties in a new family of [Cu₄Ln] (Ln^III = Gd, Tb, Dy) clusters

P. Richardson, D. I. Alexandropoulos, L. Cunha-Silva, G. Lorusso, M. Evangelisti, J. Tang, and T. C. Stamatatos
Inorganic Chemistry Frontiers 2, 945 (2015).

Layered gadolinium hydroxides for low temperature magnetic cooling

G. Abellán, G. Mínguez Espallargas, G. Lorusso, M. Evangelisti, and E. Coronado
Chemical Communications 51, 14207 (2015).

Magnetic and magnetocaloric properties of an unusual family of carbonate-panelled [Ln^III₆Zn^II₂] cages

W. Sethi, S. Sanz, K. S. Pedersen, M. A. Sørensen, G. S. Nichol, G. Lorusso, M. Evangelisti, E. K. Brechin, and S. Piligkos
Dalton Transactions 44, 10315 (2015).

Theoretical studies on polynuclear {Cu^II₅Gd^III_n} clusters (n = 4, 2): Towards understanding their large magnetocaloric effect

T. Rajeshkumar, H. V. Annadata, M. Evangelisti, S. K. Langley, N. F. Chilton, K. S. Murray, and G. Rajaraman
Inorganic Chemistry 54, 1661 (2015).

Magnetic refrigeration and spin-lattice relaxation in gadolinium-based molecular nanomagnets

F. Luis and M. Evangelisti
S. Gao (ed.), Molecular Nanomagnets and Related Phenomena, Structure and Bonding, Springer-Verlag, Berlin, Heidelberg, 164, 431 (2015).